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The proportion of dissolved gases varies in different lavas, while the lavas themselves differ in the degree of their liquidity. Some flow out tranquilly like molten iron, others issue in a pasty condition and rapidly congeal into scoriae and clinkers. Thus within the magma itself the amount of explosive energy is far from being always the same.
It is to the co-operation of these two causes--terrestrial contraction and its effects on the one hand, and the tension of absorbed gases and vapours the other--that the phenomena of volcanoes appear to be mainly due. There is no reason to believe that modern volcanoes differ in any essential respect from those of past ages in the earth's history. It might, indeed, have been anticipated that the general energy of the planet would manifest itself in far more stupendous volcanic eruptions in early times than those of the modern period. But there is certainly no geological evidence in favour of such a difference. One of the objects of the present work is to trace the continuity of volcanic phenomena back to the very earliest epochs, and to show that, so far as the geological records go, the interior of the planet has reacted on its exterior in the same way and with the same results.
We may now proceed to inquire how far volcanoes leave behind them evidence of their existence. I shall devote the next two or three chapters to a consideration of the proofs of volcanic action furnished by the very nature of the materials brought up from the interior of the earth, by the arrangement of these materials at the surface, by the existence of the actual funnels or ducts from which they were discharged above ground, and by the disposition of the masses of rock which, at various depths below the surface, have been injected into and have solidified within the terrestrial crust.
Ancient Volcanoes: Proofs of their existence derived from the Nature of the Rocks erupted from the Earth's Interior. A. Materials erupted at the Surface--Extrusive Series. i. Lavas, their General Characters. Volcanic Cycles. ii. Volcanic Agglomerates, Breccias and Tuffs.
The materials brought by volcanic action from the earth's interior have certain common characters which distinguish them from other constituents of the terrestrial crust. Hence the occurrence of these materials on any part of the earth's surface affords convincing proofs of former volcanic eruptions, even where all outward trace of actual volcanoes may have been effaced from the topographical features of the ground.
Volcanic products may be classed in two divisions--1st, Those which have been ejected at the surface of the earth, or the Extrusive series; and 2nd, Those which have been injected into the terrestrial crust at a greater or less distance below the surface, and which are known as the Intrusive series. Extrusive rocks may be further classified in two great groups-- The Lavas, or those which have been poured out in a molten condition at the surface; and The Fragmental Materials, including all kinds of pyroclastic detritus discharged from volcanic vents.
Taking first the Extrusive volcanic rocks, we may in the present chapter consider those characters in them which are of most practical value in the investigation of the volcanic phenomena of former geological periods.
i. LAVAS
The term Lava is a convenient and comprehensive designation for all those volcanic products which have flowed out in a molten condition. They differ from each other in composition and structure, but their variations are comprised within tolerably definite limits.
As regards their composition they are commonly classed in three divisions--1st, The Acid lavas, in which the proportion of silicic acid ranges from a little below 70 per cent upwards; 2nd, The Intermediate lavas, wherein the percentage of silica may vary from 55 to near 70; and 3rd, The Basic lavas, where the acid constituent ranges from 55 per cent downwards. Sometimes the most basic kinds are distinguished as a fourth group under the name of Ultrabasic, in which the percentage of silica may fall below 40.
The structures of lavas, however, furnish their most easily appreciated characteristics. Four of these structures deserve more particular attention: 1st, Cellular, vesicular or pumiceous structure; 2nd, The presence of glass, or some result of the devitrification of an original glass; 3rd, Flow-structure; and 4th, The arrangement of the rocks in sheets or beds, with columnar and other structures.
This structure, though eminently characteristic of superficial lavas, is not always by itself sufficient to distinguish them from the intrusive rocks. Examples will be given in later chapters where dykes, sills and other masses of injected igneous material are conspicuously cellular in some parts. But, in such cases, the cavities are generally comparatively small, usually spherical or approximately so, tolerably uniform in size and distribution, and, especially when they occur in dykes, distributed more particularly along certain lines or bands, sometimes with considerable regularity .
In many cases the vesicles extend through the whole thickness of a lava. Frequently they may be found most developed towards the top and bottom; the central portion of the sheet being compact, while the top and bottom are rugged, cavernous or scoriaceous.
Though originally the vesicles and cavernous spaces, blown open by the expansion of the vapours dissolved in molten lava, remained empty on the consolidation of the rock, they have generally been subsequently filled up by the deposit within them of mineral substances carried in aqueous solution. The minerals thus introduced are such as might have been derived from the removal of their constituent ingredients by the solvent action of water on the surrounding rock. And as amygdaloids are generally more decayed than the non-vesicular lavas, it has been generally believed that the abstraction of mineral material and its re-deposit within the steam-vesicles have been due to the influence of meteoric water, which at atmospheric temperatures and pressures has slowly percolated from the surface through the cellular lava, long after the latter had consolidated and cooled, and even after volcanic energy at the locality had entirely ceased.
Examples, however, are now accumulating which certainly prove that, in some cases, the vesicles were filled up during the volcanic period. Among the Tertiary basalt-plateaux of the Inner Hebrides, for instance, it can be shown that the lavas were already amygdaloidal before the protrusion of the gabbros and granophyres which mark later stages of the same continuous volcanic history, and even before the outpouring of much of the basalt of these plateaux. Not improbably the mineral secretions were largely due to the influence of hot volcanic vapours during the eruption of the basalts. This subject will be again referred to in the description of the Tertiary volcanic series.
Vesicular structure is more commonly and perfectly developed among the lavas which are basic and intermediate in composition than among those which are acid.
Striking evidence of the former glassy, and therefore molten, condition of many rocks now lithoid is to be gained by the examination of thin slices of them under the microscope. Not only are vestiges of the original glass recognizable, but the whole progress of devitrification may be followed into a crystalline structure. The primitive crystallites or microlites of different minerals may be seen to have grouped themselves together into more or less perfect crystals, while scattered crystals of earlier consolidation have been partially dissolved in and corroded by the molten glass. These and other characteristics of once fused rocks have to a considerable extent been imitated artificially by MM. Fouqu? and Michel L?vy, who have fused the constituent minerals in the proper proportions.
Since traces of glass or of its representative devitrified structures are so abundantly discoverable in lavas, we may infer the original condition of most lavas to have been vitreous. Where, for instance, the outer selvages of a basic dyke or sill are coated with a layer of black glass which rapidly passes into a fine-grained crystalline basalt, and then again into a more largely crystalline or doleritic texture in the centre, there can be no hesitation in believing that glassy coating to be due to the sudden chilling and consolidation of the lava injected between the cool rocks that enclose it. The part that solidified first may be regarded as probably representing the condition of the whole body of lava at the time of intrusion. The lithoid or crystalline portion between the two vitreous outer layers shows the condition which the molten rock finally assumed as it cooled more slowly.
Some lavas, such as obsidians and pitchstones, have consolidated in the glassy form. More usually, however, a lithoid structure has been developed, the original glass being only discoverable by the microscope, and often not even by its aid. Two varieties of devitrification may be observed among lavas, which, though not marked off from each other by any sharp lines, are on the whole distinctive of the two great groups of acid and basic rocks.
Among the acid rocks, what is called the Felsitic type of devitrification is characteristic. Thus, obsidians pass by intermediate stages from a clear transparent or translucent glass into a dull flinty or horny mass. When thin slices of these transitional forms are examined under the microscope, minute hairs and fibres or trichites, which may be observed even in the most perfectly glassy rocks, are seen to increase in number until they entirely take the place of the glass. Microlites of definite minerals may likewise be observed, together with indefinite granules, and the rock finally becomes a rhyolite, felsite or allied variety .
Some felsitic lavas possess a peculiar nodular structure, which was developed during the process of consolidation. So marked does this arrangement sometimes become that the rocks which display it have actually been mistaken for conglomerates. It is well exhibited among the Lower Silurian lavas of Snowdon, the Upper Silurian lavas of Dingle, and the Lower Old Red Sandstone lavas near Killarney.
The second type of devitrification, conspicuous in rocks of more basic composition, is marked by a more complete development of crystallization. Among basic, as among acid rocks, there are proofs of the consolidation of definite minerals at more than one period. Where the molten material has suddenly cooled into a black glass, porphyritic felspars or other minerals are often to be seen which were already floating in the magma in its molten condition. During devitrification, however, other felspars of a later period of generation made their appearance, but they are generally distinguishable from their predecessors. Probably most basic and intermediate rocks, when poured out at the surface as lavas, were no longer mere vitreous material, but had already advanced to various stages of progress towards a stony condition. These stages are still to some extent traceable by the aid of the microscope.
Microlites of the component minerals are first developed, which, if the process of aggregation is not arrested, build up more or less perfect crystals or crystalline grains of the minerals. Eventually the glass may be so completely devitrified by the development of its constituent minerals as to be wholly used up, the rock then becoming entirely crystalline, or to survive only in scanty interstitial spaces. In the family of the basalts and dolerites the gradual transition from a true glass into a holocrystalline compound may be followed with admirable clearness. The component minerals have sometimes crystallized in their own distinct crystallographic forms ; in other cases, though thoroughly crystalline, they have assumed externally different irregular shapes, fitting into each other without their Proper geometric boundaries .
Flow-structure is most perfectly developed among the obsidians, rhyolites, felsites and other acid rocks, of which it may be said to be a frequently conspicuous character . In these rocks it is revealed by the parallel arrangement of the minute hair-like bodies and crystals, or by alternate layers of glassy and lithoid material. The streaky lines thus developed are sometimes almost as thin and parallel as the leaves of a book. But they generally show interruptions and curvatures, and may be seen to bend round larger enclosed crystals, or to gather into eddy-like curves, in such a manner as vividly to portray the flow of a viscous substance. These lines represent on a minute scale the same flow-structure which may be traced in large sheets among the lavas. The porphyritic crystals and the spherulites are also drawn out in rows in the same general direction. Sometimes, indeed, the spherulites have been so symmetrically grouped in parallel rows that they appear as rod-like aggregates which extend along the margin of a dyke.
Among lavas of more basic composition flow-structure is not so often well displayed. It most frequently shows itself by the orientation of porphyritic felspars or of lines of steam-vesicles. Occasionally, however, sheets of basalt may be found in which a distinct streakiness has been developed owing to variations in the differentiation of the original molten magma. A remarkable and widespread occurrence of such a structure is met with among the Tertiary basalt-plateaux of the Inner Hebrides and the Faroe Islands. In the lower parts of these thick accumulations of successive lava-sheets, a banded character is so marked as to give the rocks the aspect of truly stratified deposits. The observer, indeed, can hardly undeceive himself as to their real nature until he examines them closely. As a full description of this structure will be given in a later chapter, it may suffice to state here that the banding arises from two causes. In some cellular lavas, the vesicles are arranged in layers which lie parallel with the upper and under surfaces of the sheets. These layers either project as ribs or recede into depressions along the outcrop, and thus impart a distinctly stratified aspect to the rock. More frequently, however, the banded structure is produced by the alternation of different varieties of texture, and even of composition, in the same sheet of basalt. Lenticular seams of olivine-basalt may be found intercalated in a more largely crystalline dolerite. These differences appear to point to considerable variations in the constitution of the magma from which the lavas issued--variations which already existed before the discharge of these lavas, and which showed themselves in the successive outflow of basaltic and doleritic material during the eruption of what was really, as regards its appearance at the surface, one continuous stream of molten rock. It is impossible to account for such variations in the same sheet of lava by any process of differentiation in the melted material during its outflow and cooling. Analogous variations occur among the basic sills and bosses of the Tertiary volcanic series of Britain. These, as will be more fully discussed in later chapters, indicate a considerable amount of heterogeneity in the deep-seated magma from which the intrusive sheets and bosses were supplied .
It is a common error to assume that flow-structure is a distinctive character of lavas that have flowed out at the surface. In reality some of the most perfect examples of the structure occur in dykes and sills, both among acid and basic rocks. Innumerable instances might be quoted from the British Isles in support of this statement.
Although, in the vast majority of cases, the presence of flow-structure may be confidently assumed to indicate a former molten condition of the rock in which it occurs, it is not an absolutely reliable test for an igneous rock. Experiment has shown that under enormous pressure even solid metals may be made to flow into cavities prepared for their reception. Under the vast compression to which the earth's crust is subjected during terrestrial contraction, the most obdurate rocks are crushed into fragments varying from large blocks to the finest powder. This comminuted material is driven along in the direction of thrust, and when it comes to rest presents a streakiness, with curving lines of flow round the larger fragments, closely simulating the structure of many rhyolites and obsidians. It is only by attention to the local surroundings that such deceptive resemblances can be assigned to their true cause.
The length of a lava-stream may vary within wide limits. Sometimes an outflow of lava has not reached the base of the cone from the side of which it issued, like the obsidian stream on the flanks of the little cone of the island of Volcano. In other cases, the molten rock has flowed for forty or fifty miles, like the copious Icelandic lava-floods of 1783. In the basalt-plateaux of the Inner Hebrides a single sheet may sometimes be traced for several miles.
The precipitation of a lava-stream into a lake or the sea may cause the outer crust of the rock to break up with violence, so that the still molten material inside may rush into the water. Some basic lavas on flowing into water or into a watery silt have assumed a remarkable spheroidal sack-like or pillow-like structure, the spheroids being sometimes pressed into shapes like piles of sacks. A good instance of this structure occurs in a basalt at Acicastello in Sicily. A similar appearance will be described in a later chapter as peculiarly characteristic of certain Lower Silurian lavas associated with radiolarian cherts in Britain and in other countries .
It probably seldom happens that a solitary sheet of lava occurs among non-volcanic sedimentary strata, with no other indication around it of former volcanic activity. Such an isolated record does not seem to have been met with in the remarkably ample volcanic register of the British Isles. The outpouring of molten rock has generally been accompanied with the ejection of fragmentary materials. Hence among the memorials of volcanic eruptions, while intercalated lavas are generally associated with sheets of tuff, bands of tuff may not infrequently be encountered in a sedimentary series without any lava. Instances in illustration of these statements may be culled from the British Palaeozoic formations back even into the Cambrian system.
A characteristic feature of some interest in connection with the flow of lava is the effect produced by it on the underlying rocks. If these are not firmly compacted they may be ploughed up or even dislocated. Thus the tuffs of the Velay have sometimes been plicated, inverted, and fractured by the movement of a flowing current of basalt. The great heat of the lava has frequently induced considerable alteration upon the underlying rocks. Induration is the most common result, often accompanied with a reddening of the altered substance. Occasionally a beautifully prismatic structure has been developed in the soft material immediately beneath a basalt, as in ferruginous clay near the village of Esplot in the Velay, in which the close-set columns are 50 centimetres long and 4 to 5 centimetres in diameter. Changes of this nature, however, are more frequent among sills than among superficial lavas. Many examples of them may be gathered from the Scottish Carboniferous districts.
Variations of structure in single lava-sheets.--From what has been said above in regard to certain kinds of flow-structure among basic rocks, it will be evident that some considerable range of chemical, but more particularly of mineralogical, composition may be sometimes observed even within the same sheet of lava. Such differences, it is true, are more frequent among intrusive rocks, especially thick sills and large bosses. But they have been met with in so many instances among superficial lavas as to show that they are the results of some general law, which probably has a wide application among the surface-products of volcanic action. Scrope expressed the opinion that in the focus of a volcano there may be a kind of filtration of the constituents of a molten mass, the heavier minerals sinking through the lighter, so that the upper portions of the mass will become more felspathic and the lower parts more augitic and ferruginous.
Leopold von Buch found that in some of the highly glassy lavas of the Canary Islands the felspar increases towards the bottom of the mass, becoming so abundant as almost to exclude the matrix, and giving rise to a compound that might be mistaken for a primitive rock.
Darwin observed that in a grey basalt filling up the hollow of an old crater in James Island, one of the Galapagos group, the felspar crystals became much more abundant in the lower scoriaceous part, and he discussed the question of the descent of crystals by virtue of their specific gravity through a still molten lava.
Mr. Clarence King during a visit to Hawaii found that in every case where he broke newly-congealed streamlets of lava, "the bottom of the flow was thickly crowded with triclinic felspars and augites, while the whole upper part of the stream was of nearly pure isotropic and acid glass." This subject will be again referred to when we come to discuss the characters of intrusive sills and bosses, for it is among them that the most marked petrographical variations may be observed. Examples will be cited both from the intrusive and extrusive volcanic groups of Britain.
Volcanic cycles.--Closely related to the problem of the range of structure and composition in a single mass of lava is another problem presented by the remarkable sequence of different types of lava which are erupted within a given district during a single volcanic period. Nearly thirty years ago Baron von Richthofen drew attention to the sequence of volcanic materials erupted within the same geographical area. He showed, more especially from observations in Western America, that a definite order of appearance in the successive species of lava could be established, the earliest eruptions consisting of materials of an intermediate or average composition, and those of subsequent outflows becoming on the whole progressively more acid, but finishing by an abrupt transition to a basic type. His sequence was as follows: 1. Propylite; 2. Andesite; 3. Trachyte; 4. Rhyolite; 5. Basalt. This generalisation has been found to hold good over wide regions of the Old World as well as the New. It is not, however, of universal application. Examples are not uncommon of an actual alternation of acid and basic lavas from the same, or at least from adjacent vents. Such an alternation occurs among the Tertiary eruptions of Central France and among those of Old Red Sandstone age in Scotland.
The range of variation in the nature of the eruptive rocks during the whole of a volcanic period in any district may be termed "a volcanic cycle." In Britain, where the records of many volcanic periods have been preserved, a number of such cycles may be studied. In this way the evolution of the subterranean magma during one geological age may be compared with that of another. It will be one of the objects of the following chapters to trace out this evolution in each period where the requisite materials for the purpose are available. We shall find that back to Archaean time a number of distinct cycles may be observed, differing in many respects from each other, but agreeing in the general order of development of the successive eruptions. Leaving these British examples for future consideration, it may be useful to cite here a few from the large series now collected from the European continent and North America.
Among the older rocks of the European continent, Prof. Br?gger has shown that in the Christiania district the eruptive rocks which traverse the Cambrian and Silurian formations began with the outburst of basic material such as melaphyre, augite-porphyrite, and gabbro-diabase, having from about 44 to about 52 per cent of silica. These were followed by rocks with a silica-percentage ranging from about 50 to 61, including some characteristic Norwegian rocks, like the rhomben-porphyry. The acidity continued to increase, for in the next series of eruptions the silica-percentage rose to between 60 and 67, the characteristic rock being a quartz-syenite. Then came deep-seated protrusions of highly acid rocks, varieties of granite, containing from 68 to 75 per cent of silica. The youngest eruptive masses in the district show a complete change of character. They are basic dykes .
The same author institutes a comparison between the post-Silurian eruptive series of Christiania and that of the Triassic system in the Tyrol, and believes that the two cycles closely agree.
During Tertiary time in Central France more than one cycle may be made out in distinct districts. Thus in the Velay, during the Miocene Period, volcanic activity began with the outpouring of basalts, followed successively by trachytes, labradorites and augitic andesites, phonolites and basalts. The Pliocene eruptions showed a reversion to the intermediate types of augitic andesites and trachytes, followed by abundant basalts, which continued to be poured forth in Pleistocene time.
Further north, in Auvergne, where the eruptions come down to a later period, the volcanic sequence appears to have been first a somewhat acid group of lavas , followed by a series of basalts, then by andesites and labradorites, the latest outflows again consisting of basalts.
Not less striking is the succession of lavas in the Yellowstone region, as described by Mr. Iddings. The first eruptions consisted of andesites. These were followed by abundant discharges of basalt, succeeded by later outflows of andesite, and of basalt like that previously erupted. After a period of extensive erosion, occupying a prolonged interval of time, volcanic energy was renewed by the eruption of a vast flood of rhyolite, after which came a feebler outflow of basalt that brought the cycle to a close, though geysers and fumaroles show that the volcanic fires are not yet entirely extinguished below.
But not only is there evidence of a remarkable evolution or succession or erupted material within the volcanic cycle of a single geological period. One of the objects of the present work is to bring forward proofs that such cycles have succeeded each other again and again, at widely separated intervals, within the same region. After the completion of a cycle and the relapse of volcanic energy into repose, there has been a renewal of the previous condition of the subterranean magma, giving rise ultimately to a similar succession of erupted materials.
If we are at a loss to account for the changes in the sequence of lavas during a single volcanic cycle, our difficulties are increased when we find that in some way the magma is restored each time to somewhat the same initial condition. Analogies may be traced between the differentiation which has taken place within a plutonic intrusive boss or sill and the sequence of lavas in volcanic cycles. It can be shown that though the original magma that supplied the intrusive mass may be supposed to have had a fairly uniform composition deep down in its reservoir, differentiation set in long before the intrusive mass consolidated, the more basic constituents travelling outwards to the margin and leaving the central parts more acid. If some such process takes place within a lava-reservoir, it may account for a sequence of variations in composition. But this would not meet all the difficulties of the case, nor explain the determining cause of the separation of the constituents within the reservoir of molten rock, whether arising from temperature, specific gravity, or other influence. This subject will be further considered in connection with intrusive Bosses.
Another fact which may be regarded as now well established is the persistence of composition and structure in the lavas of all ages. Notwithstanding the oft-repeated cycles in the character of the magma, the materials erupted to the surface, whether acid or basic, have retained with wonderful uniformity the same fundamental characteristics. No part of the contribution of British geology to the elucidation of the history of volcanic action is of more importance than the evidence which it furnishes for this persistent sameness of the subterranean magma. An artificial line has sometimes been drawn between the volcanic products of Tertiary time and those of earlier ages. But a careful study of the eruptive rocks of Britain shows that no such line of division is based upon any fundamental differences.
The chief lavas found in Britain.--Of the lavas which have been poured out at the surface within the region of the British Isles, the following varieties are of most frequent occurrence. In the acid series are Rhyolites and Felsites, but the vitreous forms are probably all intrusive. The intermediate series is represented by Trachytes and Andesites , which range from a glassy to a holocrystalline structure. The basic series includes Dolerites, Diabases, Basalts, Limburgites , and Picrites or other varieties of Peridotites. The intrusive rocks display a greater variety of composition and structure.
ii. VOLCANIC AGGLOMERATES, BRECCIAS AND TUFFS
The coarser fragmentary materials thrown from volcanic vents are known as Agglomerates where they show no definite arrangement, and especially where they actually fill up the old funnels of discharge. When they have accumulated in sheets or strata of angular detritus outside an active vent they are termed Breccias, or if their component stones have been water-worn, Conglomerates. The finer ejected materials may be comprehended under the general name of Tuffs.
It will be obvious that where the component materials of such fragmentary accumulations consist entirely of non-volcanic rocks, great caution must be exercised in attributing them to volcanic agency. Two sources of error in such cases may here be pointed out. In the first place, where angular detritus has been precipitated into still water, as, for instance, from a crag or rocky declivity into a lake, a very coarse and tumultuous kind of breccia may be formed. It is conceivable that, in course of time, such a breccia may be buried under ordinary sediments, and may thereby be preserved, while all trace of its parent precipice may have disappeared. The breccia might resemble some true volcanic agglomerates, but the resemblance would be entirely deceptive.
In the second place, notice must be taken of the frequent results of movements within the terrestrial crust, whereby rocks have not only been ruptured but, as already pointed out, have been crushed into fragments. In this way, important masses of breccia or conglomerate have been formed, sometimes running for a number of miles and attaining a breadth of several hundred feet. The stones, often in huge blocks, have been derived from the surrounding rocks, and while sometimes angular, are sometimes well-rounded. They are imbedded in a finer matrix of the same material, and may be scattered promiscuously through the mass, in such a way as to present the closest resemblance to true volcanic breccia. Where the crushed material has included ancient igneous rocks it might deceive even an experienced geologist. Indeed, some rocks which have been mapped and described as volcanic tuffs or agglomerates are now known to be only examples of "crush-conglomerates."
Not only have vast quantities of detritus of non-volcanic rocks been shot forth from volcanic vents, but sometimes enormous solid masses of rock have been brought up by ascending lavas or have been ejected by explosive vapours. Every visitor to the puys of Auvergne will remember the great cliff-like prominence of granite and mica-schist which, as described long ago by Scrope, has been carried up by the trachyte of the Puy Chopine, and forms one of the summits of the dome . The same phenomenon is observable at the Puy de Montchar, where large blocks of granite have been transported from the underlying platform. Abich has described some remarkable examples in the region of Erzeroum. The huge crater of Palandok?n, 9687 feet above the sea contains, in cliff-like projections from its walls as well as scattered over its uneven bottom, great masses of marmorised limestone and alabaster, associated with pieces of the green chloritic schists, serpentines and gabbros of the underlying non-volcanic platform. These rocks, which form an integral part of the structure of the crater, have been carried up by masses of trachydoleritic, andesitic and quartz-trachytic lavas. Examples will be given in a later chapter showing how gigantic blocks of mica-schist and other rocks have been carried many hundred feet upwards and buried among sheets of lava or masses of agglomerates during the Tertiary volcanic period in Britain .
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